Product ID:1509 NAVAJO WHITE, INDUSTRIAL MAINTENANCE & (SUP DAT)
MSDS Date:09/01/1996
FSC:8010
NIIN:00N090349
Status Code:A
MSDS Number: CHYJQ

SHERWIN-WILLIAMS CO

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-566-2917

Info Phone: 800-777-2966

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760.0

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

780.0

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 6%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

7.1

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 7%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.5

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: 1%

OSHA PEL 100 PPM

ACGIH TLV: C 50 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

160.0

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 42%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 7.2%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-HEXANONE; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 2%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/75 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 6%

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 5-10%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

BARIUM (COMPOUND) (SARA 313)

CAS: 7440-39-3

RTECS: CQ8370000

Fraction By Weight: 0.1%

OSHA PEL 0.5 MG/M3

ACGIH TLV: N/K

43.4; VOC

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

IN WORKPLACE. REPORTS HAVE ASSOC REPEATED

RTECS: 9999999ZZ

DO NOT INCINERATE. DEPRESSURIZE CONTAINER.

RTECS: 9999999ZZ

CONSULT NFPA CODE. USE APPRVD BONDING &

RTECS: 9999999ZZ

INCIN/EXPOSE TO TEMPS ABOVE 120F. HEAT FROM

RTECS: 9999999ZZ

SOURCES COULD CAUSE CONTR TO BURST. DO NOT TAKE

RTECS: 9999999ZZ

MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS

RTECS: 9999999ZZ

CLASSIFIED AS NUISANCE PARTICULATES LISTED AS

RTECS: 9999999ZZ

ONLY DURING SANDING OR ABRADING OF THE DRIED FILM.

RTECS: 9999999ZZ

GENERATED FROM THIS PRODUCT, UNDERLYING PAINT,

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, & LOSS OF
COORD ARE INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY MISTS. REDNESS
& ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CHRONIC: PRLNG OVEREXP TO SOLV INGS
MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING,
CARDIOVASCULAR, & REPRO SYS. METHYL ETHYL KETONE MAY INCR NERV SYS
EFTS OF OTHER SOLVS. RATS EXPO SED TO TITANIUM DIOXIDE DUST AT 250
MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT
ATTAINABLE (ING 13)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAM CLOTHING
& LAUNDER BEFORE REUSE. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR AT
LEAS T 15 MINUTES. GET MEDICAL ATTENTION. INGEST: NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING.
GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:1.0%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ ARE
PREF. WATER MAY BE USED TO COOL CLSD (SUP DAT)
Unusual Fire/Explosion Hazard:CLSD CONTRS MAY EXPLODE DUE TO BUILD-UP
OF PRESS WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC
EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS, & OPEN
FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLO. USE ONLY W/ADEQ
VENT. AVOID BRTHG VAP & SPRAY MIST.
Other Precautions:AVOID CONT W/SKIN & EYES. DURING USE & UNTIL ALL
VAPORS ARE GONE: KEEP AREA VENTILATED; DO NOT SMOKE; EXTINGUISH ALL
FLAMES, PILOT LIGHTS, & HEATERS; TURN OFF STOVES, ELECTRICAL TOOLS
& APPLIANCES, & ANY OTHER SOURCES OF IGNITION. (ING 15)

Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, USE PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD
BY NIOSH FOR PROT. WHEN SANDING/ABRADING DRIED FILM, USE DUST/MIST
RESP APPRVD BY NIOS H FOR DUST WHICH MAY BE (ING 20)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94/107/108.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USE.
Supplemental Safety and Health
TRADE NAME/PART #: TOUCH UP SPRAY COLORS. FIRE FIGHT PROC: CONTRS TO
PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME
HEAT. EXPLO HAZ: SURFS REQUIRES SPECIAL PREC. DURING EMER CNDTNS
OVEREXP TO DECOMP PRODS MAY CAUSE HLTHHAZ. SYMPS MAY NOT BE IMMED
APPARENT. OBTAIN MED ATTN.

Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NAVAJO WHITE.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED IN
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING METHYL
ETHYL KETONE/COPPER M AY REQUIRE TESTING FOR EXTRACTABILITY. (ING
14)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.